合成氣甲烷化制天然氣通過(guò)鑒定

800·化工進(jìn)展2012年第31卷[31] Dumesic J A, Roman-Leshkov Y. Solvent effects on fructose383:149-155.dehydration to 5-hydroxymethylfurfural in biphasic systems saturated [44] Qi W, Huang R L, Su R X, et al. Syntheses of 5-hydroxymethylwith inorganic salts[J]. Top. Catal., 2009, 52: 297-303furfural and levoglucosan by selective dehydration of glucose using[32] Davis M E, Nikolla E N E, Roman-Leshkov Y, et al. One-potsolid acid and base catalysts [J]. Chem. Commum., 2010, 46ynthesis of 5-(hydroxymethyl) furfural from carbohydrates usingl115-1117ta zeolite []. ACS Catal, 2011, 1: 408-410[45] Watanabe M, Aizawa Y, lida T, et al. Catalytic glucose and fructose33] Mizuno N, Yamaguchi K, Sakurada T. Tin-tungsten mixed oxide asconversions with TiO and ZrO2 in water at 473 K: Relationshipefficient heterogeneous catalyst for conversion of saccharides to furanbetween reactivity and acid-base property determined by TPDmeasurement [ J]. AppL. Catal. A: Gen, 2005, 295: 150-156[34] Hansen T S, Mielby J, Riisager A Synergy of boric acid and added [46] Watanabe M, Qi X H, Aida T M, et al. Catalytical conversion ofsalts in the catalytic dehydration of hexoses tofructose and glucose into 5-hydroxymethylfurfural in hot compressed5-hydroxymethylfurfural in water [] Green Chem., 2011, 13water by microwave heating [. Catal. Commun., 2008, 909-142244-2249[35] Yu H B, Wang P, Zhan S H, et al. Catalytic hydrolysis of [47] Yan HP, Yang Y, Tong D M, et al. Catalytic conversion of glucoselignocellulosic biomass into 5-hydroxymethylfurfural in ionic liquidto 5-hydroxymethylfurfural over SO4/ZrO2 and SO4"/ZrO2-Al2O3[]. Bioresou; Technol.,2011,102:4179-4183solid acid catalysts []. Catal. Comm[36] Hu S Q, Zhang Z F, Song J L, et al. Efficient conversion of glucose [48] Valente AA, Lima S, Dias AS, et al. Isomerization of D-glucose tohydroxymethylfurfural catalyzed by a common Lewis acidD-fructose over metallosilicate solid bases []. Appl CataL. A: GenSnCI(4)in an ionic liquid []. Green Chem., 2009, 11: 1746-17492008,339:21-27[37] Chung C H, Chun J A, Lee J w, et al. Catalytic production of[491 Ebitani K, Takagaki A, Ohara M, et al. A one-pot reaction for1-methyl-3-biorefinery: Combination of solid acid and base catalysts for directctylimidazolium chloride ionic liquid [] Korean J. Chem. Engproduction of 5-hydroxymethylfurfural from saccharides[J]. Chem2010,27:930-935Commun,2009,(41),6276-6278[38] Fang Z J, Zheng B H, Cheng J, et al. Microwave-assisted comversion [50] Christensen C H, Taarning E, Saravanamurugan S, et al. Zeolite-of carbohydrates into 5-hydroxymethylfurfural catalyzed by ZnClJ]catalyzed isomerization of triose sugars []. Chem. Sus. Chem, 2009aturforsch, B: Chem. Sci., 2010, 65: 168-172.625-627[39] Heeres H J, Rasrendra C B, Makertihartha IG B N, et al. Green[51] Davis M E, Moliner M, Roman-Leshkov Y P. Tin-containing zeoliteschemicals from D-glucose: Systematic studies on catalytic effects ofare highly active catalysts for the isomerization of glucose in water [1Its on the chemoselectivity and yield in aqueousNatl. Acad. Sci USA, 2010, 107: 6164-61csolutions [J]. Top. Ce2010,53:1241-1247[ 52] Hansen T S, Mielby J, Riisager A Synergy of boric acid and added[40] Pijnenburg H C M, Kuster B F M, Vanderbaan H S SinIts in the catalytic dehydration of hexoses toisomerization and hydrogenation of glucose in alkali solutions[J]5-hydroxymethylfurfural in water []. Green Chem., 2011, 13:Starke,1978,30:199205109-11[41]Beenackers J A W M, Kuster B F M, Vanderbaan H S. Physica53 Du Y G, Yang F L, Liu Q S, et al. Conversion of biomass into5-hydroxymethylfurfural using solid acid catalyst [J]. Bioresourof hexoses [J]. Appl. CataL., 1985, 16: 75-87.Techno.,2011,102:3424-3429[42] Lecomte J, Finiels A, Moreau C. Kinetic study of the isomerization of [54] Wang X H, Zhao QA, Wang L, ct al. High selective production ofglucose into fructose in the presence of anion-modified hydrotalcites5-hydroymethylfurfural from fructose by a solid heteropolyacid[ Starch- Starke,2002,54:75-7[43] Ebitani K, Ohara M, Takagaki A, et al. Syntheses of 5-hydroxy- [55] Wang X H, Fan CY, Guan H Y, et al. Conversion of fructose andmethylfurfural and levoglucosan by selective dehydration of glucoseusing solid acid and base catalysts []. AppL. Catal. A: Gen, 2010heteropolyacid salt [] Biomass Bioenergy, 2011. 35: 2659-2665技術(shù)信息合成氣甲烷化制天然氣通過(guò)鑒定研發(fā)了系列甲烷催化燃燒整體結構催化劑并進(jìn)行了工程放2月21日,中國科學(xué)院大連化學(xué)物理研究所承擔的國大,在低濃度甲烷流向換工共系統集成方面取得了顯著(zhù)進(jìn)家863計劃項目——合成氣甲烷化制天然氣通過(guò)了專(zhuān)家驗展,申請發(fā)中國煤化工收。專(zhuān)家稱(chēng),該成果有望成為替代國外甲烷化催化劑和工藝大連化CNMHG甲烷化催化劑研制的技術(shù)。及放大生產(chǎn)、甲烷化反應器及其工藝設計,以及多段循環(huán)甲據悉,研究組針對中低甲烷濃度煤層氣的治理與利用,烷化工藝集成等關(guān)鍵核心技術(shù)方面取得了實(shí)質(zhì)性進(jìn)展。